dc.contributor.advisor	Metre, Ramesh K.
dc.creator.researcher	Mishra, Abhishek.
dc.date.accessioned	2023-12-06T10:42:36Z
dc.date.available	2023-12-06T10:42:36Z
dc.date.awarded	2022
dc.date.issued	2022-11
dc.date.registered	2017
dc.description.abstract	Molecular materials based on organometallic complexes have witnessed significant attention in the past few years due to their solution processability, flexibility in designing, and ease of device fabrication. Molecular organometallic complexes have been considered the potential candidates to address various challenges in the area of molecular electronics, such as data storage and data handling. Various electronic devices using the molecular system are being explored continuously. On the other hand, the coordination chemistry of molecular organotin complexes is well documented in the literature. Organotin complexes exhibit a wide range of fascinating structures because of the highly expandable coordination site of the tin atom. Organotin complexes, that are studied, are comprised of two major classes; one containing Sn-S unit in their structure known as organotin sulfides, and the other containing Sn-O unit in their structure known as organostannoxanes. Unlike organostannoxanes, the structural chemistry of organotin sulfides is not much explored. Intramolecular coordination appears to be crucial in terms of stabilizing unique structural motifs in organotin complexes. There are limited reports on O?Sn and N?Sn intramolecularly coordinated organotin complexes in the literature. Although organotin complexes are explored for their vast structural diversity, they are not explored as molecular materials. This thesis is focused majorly on the synthesis and structural characterization of new organotin complexes using the intramolecular N?Sn coordination approach and their applications as molecular materials and biological activity. In the quest to search for new molecular materials, we have successfully demonstrated a molecular memory device based on a tetranuclear organotin sulfide cage, negative differential resistance (NDR) device based on a dinuclear hydroxo-methoxo bridged organostannoxane, and a novel dodecanuclear oxo-hydroxo Sn12 cage cluster. Apart from the device properties, biological studies were also explored for a dinuclear organotin sulfide and a few organostannoxanes, which showed significant bactericidal activity against both gram-positive (M. luteus) and negative (E. coli) bacteria. The structural features involving the role of intramolecular N?Sn coordination were also examined for various organostannoxanes.	en_US
dc.description.note	col. ill.; including bibliography	en_US
dc.description.statementofresponsibility	By Abhishek Mishra	en_US
dc.format.accompanyingmaterial	CD	en_US
dc.format.extent	xxiii, 144 p.	en_US
dc.identifier.accession	TP00123
dc.identifier.citation	Mishra, Abhishek. (2022). Organotin Assemblies Containing Sn-S and Sn-O Units: Applications in Resistive Switching Device and Antibacterial Properties (Doctor's thesis). Indian Institute of Technology Jodhpur, Jodhpur.	en_US
dc.identifier.uri	https://ir.iitj.ac.in/handle/123456789/133
dc.language.iso	en
dc.publisher	Indian Institute of Technology Jodhpur
dc.publisher.department	Department of Chemistry	en_US
dc.publisher.place	Jodhpur
dc.rights.holder	IIT Jodhpur
dc.rights.license	CC-BY-NC-SA
dc.subject.ddc	Organotin assemblies, Sn-S units, Sn-O units, Resistive switching device, Antibacterial properties, Organotin compounds, Metal-organic frameworks (MOFs), Tin-based materials, Thin-film devices, Electrical resistance	en_US
dc.title	Organotin Assemblies Containing Sn-S and Sn-O Units: Applications in Resistive Switching Device and Antibacterial Properties	en_US
dc.type	Thesis

Organotin Assemblies Containing Sn-S and Sn-O Units: Applications in Resistive Switching Device and Antibacterial Properties

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